报告名称：Tailored Transition Metal Oxides for Sustainable Carbonaceous Fuel Conversion

报告人：Fanxing Li （李凡星）

Chemical and Biomolecular Engineering Department, North Carolina State University, USA.

时间：2016-7-8（周五）下午 2：00-3：00

地点：

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报告简介：

  As an alternative approach for carbonaceous fuel conversion and CO₂ capture, the so-called chemical looping strategy utilizes redox properties of first-row transition metal oxides to simplify the conventional energy conversion processes. In a typical chemical looping process, carbonaceous feedstock is oxidized into products such as CO₂ by active lattice oxygen (O^2-) in the transition metal oxide particles, a.k.a. oxygen carrier. In a subsequent step, the O^2--deprived oxygen carrier particles are replenished by a gaseous oxidant, generating hydrogen or heat. The cyclic redox operation, often carried out in circulating fluidized bed reactors, has the potential to significantly reduce the exergy loss for carbonaceous energy conversion and carbon dioxide capture.  

  While a number of supported metal oxides have demonstrated promising redox performances, further improvements of the activity and redox stability of these oxygen carriers are of critical importance for successful deployment of this novel technology. To date, oxygen carrier development largely relies on a trial-and-error type of approach. We present a rationalized strategy for oxygen carrier optimization: to arrive at oxygen carriers with superior activity, the rate limiting step for the redox reactions is first identified. Mixed ionic-electronic conductive support that de-bottlenecks such a rate limiting step is then used to improve the metal oxide activity by two orders of magnitude. Investigation of oxygen carrier deactivation mechanisms further sheds light for designing oxygen carriers with both high activity and extended lifetime. Besides their applications in chemical looping combustion, transition metal oxides with tailored nano-structures for methane partial oxidation and solar-based water-splitting are also exemplified. A redox based oxidative dehydrogenation process for ethylene production from ethane will be discussed in detail in terms of redox catalyst development and characterizations as well as process simulations, which indicate significant reduction in NOx and CO₂ emissions compared to state-of-the-art.

 报告人简介：

  Dr. Fanxing Li is an Associate Professor in the Chemical and Biomolecular Engineering Department at North Carolina State University. Dr. Li received his BS and MS degrees in chemical engineering from Tsinghua University in 2001 and 2004, respectively. He received his PhD at the Ohio State University in 2009 under the direction of Professor Liang-Shih Fan. Dr. Li has published 41 journal articles and book chapters. He is also an inventor/co-inventor of 11 patents and patent applications. He has won numerous awards including the Best PhD in Particle Technology Award, the U.S. National Science Foundation CAREER Award, SABIC Young Professional Award, NC State Sigma Xi Faculty Research Award, and NC State University Faculty Scholar Award.